Metal Mediated Template Synthesis of LigandsThis book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades. Contents: The Template Effect; Alkylation Reactions; Schiff Condensation; Mannich Condensation; Self Condensation of Nitriles; Self-Assembled Systems. Readership: Upper level undergraduates, graduate students, academics, researchers industrialists in inorganic, solid-state, supramolecular and organic chemistry. |
Contents
Preface | 1 |
Alkylation Reactions | 18 |
Schiff Condensation | 24 |
Self Condensation of Nitriles | 187 |
SelfAssembled Systems | 208 |
257 | |
295 | |
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Common terms and phrases
14-membered acetate acid Acta alkylation Angew anion binuclear complexes bridge cage complexes capping catenanes cation cavity CH₂ CH3 CH3 chelate ring Chem Chim chiral cobalt(III Comba complexes containing complexes show compounds condensation reaction copper(II crystal structure Cu(I Cu(II cyclization Dalton Trans derived diamine donor atoms electrochemical electronic formaldehyde formation formed H₂N helical hexaaza imine Inorg interaction ions iron(II isomer lanthanide Lawrance Lehn ligand field macrobicyclic macrocyclic complexes macrocyclic ligands magnetic manganese(II Mannich metal centres metal complexes metal directed metal ions metal template molecular molecules mononuclear NH HN NH NH NH NH₂ Ni(II nickel(II nitrate nitroethane nitrogen nitrogen atoms NO₂ nucleophilic obtained octahedral oxidation pendant pentadentate perchlorate phthalonitrile planar porphyrins precursors presence properties pyridine redox resulted rotaxanes Sargeson Sauvage Scheme Schiff base self-assembly silver(I spectra square-planar stability steric substituted template condensation template effect template reaction template synthesis transition metal trefoil knot X-ray structure yields